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Veiligheidsinformatieblad
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Chemical
name:
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IRON(III)CHLORIDE
SOLUTION
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Publicationdate:
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2003-03-05
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1 -
Identification of the substance/mixture and of the
company/undertaking
2
- Hazards identification
GHS
Classification ((EC) No 1272/2008)
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Acute
toxicity
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Category 4
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H302
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Hazardous to the
aquatic environment - chronic
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Category 2
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H411
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Skin
corrosion
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Category 1B
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H314
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EC Classification
((EC) No 67/548 or 1999/45)
• Harmful if
swallowed.
• Causes burns.
• Toxic to the aquatic
organisms, may cause long-term adverse effects in the
aquatic environment.
3 -
Composition/information on ingredients
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Component
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CAS-no
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EC-number
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Catalogue-no
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%
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GHS-Label/EC-Label
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IRON(III)CHLORIDE
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7705-08-0
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231-729-4
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≥25.0
<80.0 %
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GHS05
GHS07
GHS09
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H302
H411
H314
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Acute tox.
4
Aquatic chronic 2
Skin corr. 1B
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C,N;R: 22,34,51/53
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WATER
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7732-18-5
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231-791-2
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≥20.0
<75.0 %
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4 -
First aid measures
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Skin:
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DO NOT touch
contaminated clothes with bare hands. Remove
contaminated clothes immediately. Remove residue of
the substance from the skin (f.i. rinse with plenty
of water). In case of serious burnings bring victim
as soon as possible to the hospital, in other case
call for a doctor.
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Ingestion:
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If victim is
conscious, rinse mouth with water. DO NOT let
drink. DO NOT induce vomiting. Bring victim as soon
as possible into the hospital
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Inhalation:
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Bring victim into
the fresh air as soon as possible and let rest. In
case of severe exposure call for a doctor. In case
of breathing problems, loose squeezing clothes and
if victim is conscious bring victim in high sitting
position. In case of stagnation of breathing give
IMMEDIATELY oxygen and transport to hospital as
soon as possible.
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Eyes:
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Rinse for a long
time with plenty of water. In case of eye-sight
disturbances bring victim immediately into the
hospital, in other cases call for a doctor
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5 -
Firefighting measures
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Hazardous
decomposition products in fire:
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hydrochloric acid,
iron oxides
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Fire-extinguisher:
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determined by
surrounding
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6 -
Accidental release measures
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Spillage
procedure:
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Absorb the liquid
in appropriate absorbent (e.g. Powersorb, dry sand,
diatomite, vermiculite etc.), shovel the mixture
into plastic bags and remove to the central depot
for hazardous waste.
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7 -
Handling and storage
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Local
exhausting:
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Apply local
exhaust.
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Storage
conditions:
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in a well
ventilated area
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protected from
proximity to other sources of heat
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in a closed,
original container
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Storage code (on
behalf of PGS 15):
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C1
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8 -
Exposure controls/personal protection
Exposure
limits
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TWA(8
hours):
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1 mg/m3
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IRON(III)CHLORIDE
(as iron)
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applicable
to:
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United States of
America
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TWA(8
hours):
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1 mg/m3
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IRON(III)CHLORIDE
(as iron)
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applicable
to:
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The
Netherlands
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TWA(8
hours):
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0.1 mg/m3
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IRON(III)CHLORIDE
(as iron)
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applicable
to:
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Switzerland
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TWA(8
hours):
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1 mg/m3
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IRON(III)CHLORIDE
(as iron, inhalable dust)
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applicable
to:
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The
Netherlands
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No TWA has been
laid down.
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WATER
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C=Ceiling; S=Skin
Remarks
exposure limits:
none
Odour threshold
(20°C; 1013 mbar):
Advised
personal protection:
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Inhalation:
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none (when
sufficient exhausting)
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Skin:
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protective
clothing
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Hands:
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butyl rubber
gloves
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polyvinyl chloride
gloves
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9 -
Physical and chemical properties
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Boiling
point/range:
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>100 °C
(1013 mbar)
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Vapor
rate/range:
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not
traceable
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Melting
point/range:
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<0
°C
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Relative
density:
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≥1.200 ≤1.500
(water=1) (20 °C)
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Vapour
pressure:
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2.3 kPa (20
°C)
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Viscosity:
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≥1 ≤13
mPa.s (20 °C)
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Decomposition
temperature:
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>160
°C
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Flash
point/range:
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not
applicable
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Autoignition
temperature:
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not
applicable
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Electrostatic
chargement:
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no
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Explosive
limits:
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not
applicable
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Dust explosions
possible in air:
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not
applicable
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Solubility in
water:
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complete
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10
- Stability and reactivity
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Hazardous reactions
with:
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alkaline solutions,
metals, ethylene oxide, oxidizing substances,
halogen hydrocarbons
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Hazardous
decomposition products at heating:
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hydrochloric acid,
iron hypochlorite
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Conditions to
avoid:
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none
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11
- Toxicological information
Symptoms
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Skin
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local:
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The substance is
corrosive: redness, pain, burns, blisters.
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general:
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Probably no
absorbtion worth mentioning.
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Ingestion
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local:
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The substance is
corrosive: sore throat, abdominal pain,
nausea.
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general:
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The substance may
be absorbed after ingestion.
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Inhalation
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local:
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The substance is
with atomising corrosive: sore throat, coughing,
dyspnoea.
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general:
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Probably no
absorbtion worth mentioning.
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Eyes
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local:
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The substance is
corrosive: redness, pain, poor vision.
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Toxicity
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LD-50: 450 mg/kg
(ORL-RAT), IRON(III)CHLORIDE
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Source/Method:
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not traceable/not
traceable
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Ames test:
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not traceable
IRON(III)CHLORIDE
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Source:
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not
traceable
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not traceable
WATER
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Source:
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not
traceable
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12
- Ecological information
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Degradability:
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not traceable
IRON(III)CHLORIDE
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Biochemical
factor:
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≥2756 ≤9622
IRON(III)CHLORIDE
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Log Po/w:
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-4
IRON(III)CHLORIDE
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Ecotoxicity
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LC-50: 18.5
mg/l/96H (Fish), IRON(III)CHLORIDE
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Source/Method:
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IUCLID/not
traceable
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EC-50: 9.6 mg/l/48H
(Daphnia), IRON(III)CHLORIDE
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Source/Method:
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not traceable/not
traceable
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Remarks on
ecotoxicity:
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none
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13
- Disposal considerations
Remainder material or
uncleaned empty packagings have to be incinerated in a
proper installation or dumped on an approved landfill, in
accordance with local and national legislation.
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- Transport information
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UN-name:
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IJZER(III)CHLORIDE,
OPLOSSING
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15
- Regulatory information
 
Hazard
statements:
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H302
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Harmful if
swallowed.
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H314
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Causes severe skin
burns.
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H411
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Toxic to aquatic
life with long lasting effects.
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Precautionary
statements:
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P260.2
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Do not breathe
vapour.
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P264
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Wash hands/skin
thoroughly after handling.
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P270
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Do no eat, drink or
smoke when using this product.
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P273
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Avoid release to
the environment.
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P280.5
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Wear protective
gloves/protective clothing/eye protection/face
protection.
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P301+P330+P331
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IF SWALLOWED: rinse
mouth. Do NOT induce vomiting.
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P303+P361+P353
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IF ON SKIN (or
hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower.
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P304+P340
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IF INHALED: Remove
victim to fresh air and keep at rest in a position
comfortable for breathing.
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P305+P351+P338
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IF IN EYES: Rinse
cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue
rinsing.
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P310
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Immediately call a
POISON CENTER or doctor/physician.
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P501
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Dispose of
contents/container to a hazardous or special waste
collection point.
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Hazardous
component(s)
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IRON(III)CHLORIDE
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Labelling according
to EC directives
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51/53
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Toxic to the
aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
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26
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In case of contact
with eyes, rinse immediately with plenty of water
and seek medical advice.
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28.1
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After contact with
skin, wash immediately with plenty of water.
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36/37/39
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Wear suitable
protective clothing, gloves and eye/face
protection.
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45
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In case of accident
or if you feel unwell, seek medical advice
immediately (show the label where possible).
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60
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This material and
its container must be disposed of as hazardous
waste.
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61
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Avoid release to
the environment. Refer to special
instructions/Safety data sheets.
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Hazardous
component(s)
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IRON(III)CHLORIDE
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Remarks on
EC-labelling
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The supplier may
give a different label (Userlabel).
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16
- Other information
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Date last
update:
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2010-11-11
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Remarks on
MSDS:
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The component(s),
as mentioned in section 3, are registrated in the
Toxic Substances Control Act Inventory
(USA).
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Overview
relevant H-sentences from all components in section
3:
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H302
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Harmful if
swallowed.
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H314
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Causes severe skin
burns.
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H411
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Toxic to aquatic
life with long lasting effects.
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Overview
relevant R-sentences from all components in section
3:
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51/53
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Toxic to the
aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
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