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safety
sheet
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Chemical
name:
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POLISHING
AGENT
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Publicationdate:
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2003-03-05
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1 -
Identification of the substance/mixture and of the
company/undertaking
2
- Hazards identification
GHS
Classification ((EC) No 1272/2008)
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Hazardous to the
aquatic environment - chronic
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Category 2
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H411
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Flammable
liquid
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Category 3
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H226
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Skin
irritation
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Category 2
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H315
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Specific target
organ toxicity - single exposure
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Category 3
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H336
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EC Classification
((EC) No 67/548 or 1999/45)
• Flammable.
• Irritating to
skin.
• Toxic to the aquatic
organisms, may cause long-term adverse effects in the
aquatic environment.
• Vapours may cause
drowsiness and dizziness.
3 -
Composition/information on ingredients
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Component
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CAS-no
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EC-number
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Catalogue-no
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%
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GHS-Label/EC-Label
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STODDARD SOLVENT
(C6H6 <0.1%)
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8052-41-3
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232-489-3
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649-345-00-4
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≥50.0
<75.0 %
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GHS02
GHS07
GHS08
GHS09
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H304
H226
H315
H411
H336
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Asp. tox.
1
Flam. liq. 3
Skin irrit. 2
Aquatic chronic 2
STOT SE 3
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Xn,N;R: 10,38,51/53,65,67
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AMMONIA
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1336-21-6
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215-647-6
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007-001-01-2
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≥0.3 <1.3
%
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GHS05
GHS09
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H314
H400
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Skin corr.
1B
Aquatic acute 1
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C,N;R: 34,50
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4 -
First aid measures
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Skin:
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Remove contaminated
clothes as soon as possible. Remove residue
substance as soon as possible (e.g. rinse with
plenty of water). In case of a serious exposure
call for a doctor.
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Ingestion:
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If victim is
conscious let him drink 1 or 2 glasses of water. In
case of general disorders bring victim into the
hospital, otherwise call for a doctor.
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Inhalation:
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Bring victim into
the fresh air as soon as possible and let rest. In
case of severe exposure call for a doctor. In case
of breathing problems, loose squeezing clothes and
if victim is conscious bring victim in high sitting
position. In case of stagnation of breathing give
IMMEDIATELY oxygen and transport to hospital as
soon as possible.
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Eyes:
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Rinse for a long
time with plenty of water. In case of eye-sight
disturbances bring victim immediately into the
hospital, in other cases call for a doctor
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5 -
Firefighting measures
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Hazardous
decomposition products in fire:
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carbon monoxide,
ammonia anhydrous
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Fire-extinguisher:
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carbon dioxide,
extinguishing powder, water spray, alcohol
resistant foam
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6 -
Accidental release measures
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Spillage
procedure:
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Absorb the liquid
in appropriate absorbent (e.g. Powersorb, dry sand,
diatomite, vermiculite etc.), shovel the mixture
into plastic bags and remove to the central depot
for hazardous waste.
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7 -
Handling and storage
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Local
exhausting:
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Depends on
processing circumstances, but at least good room
ventilation.
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Storage
conditions:
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away from ignition
sources
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Storage code (on
behalf of PGS 15):
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F1
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8 -
Exposure controls/personal protection
Exposure
limits
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applicable
to:
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The
Netherlands
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TWA(8
hours):
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575 mg/m3
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STODDARD SOLVENT
(C6H6 <0.1%)
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TWA(8
hours):
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533 mg/m3
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STODDARD SOLVENT
(C6H6 <0.1%)
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applicable
to:
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United States of
America
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TWA(8
hours):
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573 mg/m3
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STODDARD SOLVENT
(C6H6 <0.1%)
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TWA(8
hours):
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200 mg/m3
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STODDARD SOLVENT
(C6H6 <0.1%) (carbonhydrogen mix, group
4)
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applicable
to:
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Switzerland
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TWA(8
hours):
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525 mg/m3
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STODDARD SOLVENT
(C6H6 <0.1%) (carbonhydrogen mix, group
4)
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TWA(8
hours):
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300 mg/m3
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STODDARD SOLVENT
(C6H6 <0.1%) (carbonhydrogen mix, group
4)
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TGG(15
minuten):
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600 mg/m3
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STODDARD SOLVENT
(C6H6 <0.1%) (carbonhydrogen mix, group
4)
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applicable
to:
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The
Netherlands
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TWA(8
hours):
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14 mg/m3
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AMMONIA (as
ammonia, anhydrous)
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TGG(15
minuten):
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36 mg/m3
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AMMONIA (as
ammonia, anhydrous)
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TWA(8
hours):
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17 mg/m3
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AMMONIA (as
ammonia, anhydrous)
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TGG(15
minuten):
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24 mg/m3
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AMMONIA (as
ammonia, anhydrous)
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applicable
to:
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United States of
America
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TWA(8
hours):
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17 mg/m3
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AMMONIA (as
ammonia, anhydrous)
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TGG(15
minuten):
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24 mg/m3
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AMMONIA (as
ammonia, anhydrous)
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TWA(8
hours):
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14 mg/m3
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AMMONIA (as
ammonia, anhydrous)
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TGG(15
minuten):
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28 mg/m3
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AMMONIA (as
ammonia, anhydrous)
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C=Ceiling; S=Skin
Remarks
exposure limits:
none
Odour threshold
(20°C; 1013 mbar):
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≥5.25 ≤157.5
mg/m3
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STODDARD SOLVENT
(C6H6 <0.1%)
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Advised
personal protection:
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Inhalation:
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none (when
sufficient exhausting)
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Skin:
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none (when used
normally)
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Hands:
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polyvinyl alcohol
gloves
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9 -
Physical and chemical properties
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Physical
state:
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viscous
liquid
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Boiling
point/range:
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not
traceable
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Vapor
rate/range:
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not
traceable
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Melting
point/range:
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not
traceable
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Relative
density:
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≥0.97500 ≤1.00000
(water=1) (20 °C)
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Vapour
pressure:
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not
traceable
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Decomposition
temperature:
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not
traceable
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Flash
point/range:
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≥38 ≤42
°C
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Autoignition
temperature:
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not
traceable
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Electrostatic
chargement:
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not
traceable
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Explosive
limits:
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not
traceable
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Dust explosions
possible in air:
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not
applicable
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Solubility in
water:
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partial
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10
- Stability and reactivity
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Hazardous reactions
with:
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strong
oxidizers
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Hazardous
decomposition products at heating:
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none
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Conditions to
avoid:
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none
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11
- Toxicological information
Symptoms
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Skin
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local:
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The substance is
irritating: redness, pain.
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Degreasing: in case
of sustained contact a rough, dry skin,
eczema.
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general:
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Probably no
absorbtion worth mentioning.
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Ingestion
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local:
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The substance is
prickling: sore throat.
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general:
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Probably no
absorbtion worth mentioning.
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Inhalation
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local:
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The vapour is in
large concentrations prickling: coughing.
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general:
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The vapour may be
absorbed by inhalation.
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The vapour is
intoxicating: sleepiness, dizziness.
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Eyes
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local:
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The substance is
prickling: redness.
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Toxicity
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LD-50: >2 g/kg
(ORL-RAT), STODDARD SOLVENT (C6H6 <0.1%)
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Source/Method:
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ChemDat (Merck)/not
traceable
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LD-50: >2 g/kg
(SKN-RBT), STODDARD SOLVENT (C6H6 <0.1%)
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Source/Method:
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CONCAWE/not
traceable
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LD-50: 350 mg/kg
(ORL-RAT), AMMONIA
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Source/Method:
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CONCAWE/not
traceable
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LC-50: 11.59
mg/l/1H (IHL-RAT), AMMONIA
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Source/Method:
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not traceable/not
traceable
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Ames test:
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not traceable
STODDARD SOLVENT (C6H6 <0.1%)
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Source:
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not
traceable
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not traceable
AMMONIA
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Source:
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not
traceable
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12
- Ecological information
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Degradability:
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not readily
biodegradable STODDARD SOLVENT (C6H6
<0.1%)
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Log Po/w:
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≥3 ≤6
STODDARD SOLVENT (C6H6 <0.1%)
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Ecotoxicity
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LC-50: >1 ≤10
mg/l/96H (Fish), STODDARD SOLVENT (C6H6
<0.1%)
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Source/Method:
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Supplier/OECD
201
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Remarks on
ecotoxicity:
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none
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13
- Disposal considerations
Remainder material or
uncleaned empty packagings have to be incinerated in a
proper installation or dumped on an approved landfill, in
accordance with local and national legislation. Uncleaned
empty packagings may contain inflammable and/or explosive
mixtures.
14
- Transport information
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UN-name:
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BRANDBARE
VLOEISTOF, N.E.G.
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15
- Regulatory information
  
Hazard
statements:
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H226
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Flammable liquid
and vapour.
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H315
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Causes skin
irritation.
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H336
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May cause
drowsiness or dizziness.
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H411
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Toxic to aquatic
life with long lasting effects.
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Precautionary
statements:
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P210
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Keep away from
heat/sparks/open flames/hot surfaces. - No
smoking.
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P240
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Ground/bond
container and receiving equipment.
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P241
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Use explosion-proof
electrical/ventilating/lighting equipment.
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P243
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Take precautionary
measures against static discharge.
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P261.2
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Avoid breathing
vapours.
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P264
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Wash hands/skin
thoroughly after handling.
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P271
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Use only outdoors
or in a well-ventilated area.
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P273
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Avoid release to
the environment.
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P280.7
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Wear protective
gloves/eye protection/face protection.
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P303+P361+P353
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IF ON SKIN (or
hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower.
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P304+P340
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IF INHALED: Remove
victim to fresh air and keep at rest in a position
comfortable for breathing.
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P312
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Call a POISON
CENTER or doctor/physician if you feel
unwell.
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P332+P313
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If skin irritation
occurs: Get medical advice/attention.
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P362
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Take off
contaminated clothing and wash before reuse.
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P403+P233+P235
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Store in a
well-ventilated place. Keep container tightly
closed. Keep cool.
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P501
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Dispose of
contents/container to a hazardous or special waste
collection point.
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Hazardous
component(s)
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not
applicable
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Labelling according
to EC directives
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51/53
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Toxic to the
aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
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67
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Vapours may cause
drowsiness and dizziness.
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23.2
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Do not breath
vapour.
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24
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Avoid contact with
skin.
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60
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This material and
its container must be disposed of as hazardous
waste.
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61
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Avoid release to
the environment. Refer to special
instructions/Safety data sheets.
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62
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If swallowed, do
not induce vomiting: seek medical advice
immediately and show this container or
label.
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Hazardous
component(s)
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not
applicable
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Remarks on
EC-labelling
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The supplier may
give a different label (Userlabel).
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16
- Other information
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Date last
update:
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2010-11-11
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Remarks on
MSDS:
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The component(s),
as mentioned in section 3, are registrated in the
Toxic Substances Control Act Inventory
(USA).
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Overview
relevant H-sentences from all components in section
3:
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H226
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Flammable liquid
and vapour.
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H315
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Causes skin
irritation.
|
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H336
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May cause
drowsiness or dizziness.
|
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H411
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Toxic to aquatic
life with long lasting effects.
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Overview
relevant R-sentences from all components in section
3:
|
|
51/53
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Toxic to the
aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
|
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|
65
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Harmful: may cause
lung damage if swallowed.
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67
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Vapours may cause
drowsiness and dizziness.
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50
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Very toxic to
aquatic organisms.
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