[1]. DRYING OF INKS.
The drying of a substance implies that a liquid or a semi-liquid substance
hardens. In the case of ink, which is made up of
pigments and of a vehicle, the
disappearence of part of the vehicle leaves the dry colour behind.
Essentially this disappearence concerns the
solvent* (water, alcohol, etc.) since the rest of the vehicle (oils,
synthetic or natural resins, and others) ensure the cohesion, the keying, and the
look of the ink.
The drying in itself does not imply that the substance having undergone this process
will not dissociate itself, will not be indelible, or will not be altered. In fact
a dry ink can usually be dissolved (see
* diluting agent, washing,
restoring , and
solvent), will often run when it comes into
contact with other inks ( see run and
bleed), with a solvent, with a vehicle*, with a
dusting agent, with a
medium, and remains more or less sensitive
to the effects of light
[* conservation,
restoring].
The drying process of ink depends on the nature of the vehicle used. The drying
process may come about in one of the following manners:
-BY EVAPORATION. This is the case for water base inks, cellulose base inks,
and (to a certain extent) oil base inks, especially if the latter are used on a
non-absorbant surface. This type of drying process requires airing in function of
the amount of ink that has been applied and in function of the atmospheric humidity.
Such drying can he accellerated by blowing hot or cold air over the surface to be
dried.
-BY PENETRATION OF THE SURFACE. This is the case with water and oil base inks
applied to absorbent surfaces [dusting agent
, paper].
-BY OXYDATION IN CONTACT WITH AIR. This is the case with oil paint and
glycerophtalic inks. The oxydation process, as opposed to penetration which is a
physical process, is nothing less than a chemical reaction of the ink with oxygen.
The oxygen coming into contact with these inks brings about polymerization and
therefore a progressive thickening of the ink until it reaches its final, hard stage.
The drying agent used accellerates the oxydation process. Heat helps to
activate drying processes depending on oxydation.
Whatever the drying process may be, all of them will be slowed down by humidity,
poor air circulation (piling up of impressions), and the acidity of the water used
to dampen the paper in lithography and offset printing.
Typographical inks dry by penetration (newspaper ink) and by means of
oxydation. Photogravure inks dry by evaporation and by penetration.
Silkscreen inks dry by means of oxydation and by penetration (in the case of
oil base inks). With cellulose and ethylcellulose base inks, fluorescent inks as
well as some synthetic inks and some water base inks, drying is achieved by
evaporation and penetration. Clycerophtalic inks dry by oxydation after the
evaporation of the solvent they contain.
Different inks have different drying times. Typographical inks are fast drying
for machine printing and medium fast drying for manual impressions. This is also
true for lithographic and offset inks which are fast drying for machine printing.
Photogravure inks (which are perforce liquid inks) are fairly quick drying due to
the volatile nature of the diluting agents used (acetone, alcohol, esters ).
The drying speed of these inks is calculated in function of the speed of the machines
used. The inks used for manual intaglio printing are fairly quick drying.
The inks used in silkscreening are more delicate and somewhat problematical
because their drying process must be slowed down so that they do not dry in the
meshes of the screen. Furthermore, in printing silkscreen images one uses brilliant
finish inks (often glycerophtalic inks) which take more than eight days to dry
completely on an absorbent surface. In order to avoid the clogging of the silkscreen
meshes a retarder is often mixed into the ink which further slows the drying of the
printed image.
Once the printing has been done it is essential that these various steps be kept in
mind: place a sheet of tissue paper between each impression using intaglio ink,
between each impression of a manually executed relief print, and between each
lithographic print. The sheets of tissue paper may be changed after a while if the
ink stains too much. The clean sheet can then be left in place for several months,
or even longer if there is danger of rubbing motion An impression will loose more
ink if the relief of the ink is high.
In silkscreening each sheet must be dried separately on a rack or hanging from a
clothes line [* dryer].
To accellerate the drying process one can provoke a draught or pulse hot air onto
the impression (unless the ink be a glycerophtalic one). Infra-red tunnels are also
used in industrial silkscreening but such drying requires much caution.
The drying time of inks is relative since it depends on the ink used as well as on
the atmospheric conditions. A printer should be able to evaluate these variables.
Actually drying time can be anywhere from less than a second to more than a month.
The drying time can be divided into two distinct phases:
the first is the dust-free drying phase, which is the amount of time it takes
for the ink to dry encugh not to catch any dust, the second phase is the
setting, which is the time it takes for the ink to dry enough not to stain
when the impressions are piled up. As long as the dust-free phase is not complete
one must be very careful, especially with very sticky inks, such as
glycerophtalic ones. The setting phase, on the other hand, is not always easy to
determine, the reason being that the size ni the pile influences the outcome of
this phase in two different ways. First of all the weight of a big pile may be
such that staining continues to appear. The second reason is that a big pile and the
consequent pressure reduce the air circulation thus slowing up the drying process.
In silkscreening and when using glycerophtalic inks in particular, the setting
process might be very slow and might still not be complete even when a finger no
longer sticks to the ink. In fact, the ink may remain pasty below a dry crust which
forms very quickly and acts as an air barrier. In such cases accidents may happen
such as sticking when the impressions are piled up. To avoid such damage
impressions whose drying point is not certain should be piled up on their sides.
The drying of inks before use is another problem that should not be forgotten;
first of all because the inks should be kept properly and secondly to reduce expenses.
Oily inks form a layer on the surface which is often called the skin.
The skin protects the ink below it from being oxydized but, in the long run, the ink
below becomes thicker and thicker until it is unusable. Synthetic inks also dry up
and form a skin which does not protect the rest of the ink from thickening.
Cellulose and ethyl cellulose inks do not dry up if they are kept in a hermetically
closed container. Glycerophtalic inks form a skin on the surface which may protect
the ink below it for quite a long time.
Varnish reacts more or less in the same way as ink. Alcohol base varnish dries by
evaporation. Oily varnish dries due to oxydation and penetration
[* ink, paper
, dryer].
[2] DRYING LITHOGRAPHIC PREPARATIONS. The drying of preparations is of great
importance in lithography. Depending on the work, drying must be done immediately
after the applications or then might be done after a varying amount of time.
Traditionally drying was done with a tourniquet or a fan but today a pulsed
air dryer is used [* lithography].
[3] DRYING LITHOGRAPHIC STONES. The stones used in lithography must be
perfectly dry before being worked on. If they are a bit damp they can be dried out
in a stove or in front of a heater. The heating of the stone must be progressive
(not brutal) and the stone must be kept standing on its side. At times this drying
process is called "making the stone perspire".
[4] DRYING PAPER . Paper used for intaglio printing is often dampened and so
is the paper used for printing relief engravings and lithographies. In the past even
paper for delicate typographical work was slightly dampened. Because of this
dampening one must then dry the paper after impression. This drying is done with the
sheets lying flat and by applying pressure [
* pressing].
The sheets that have already been printed on are put between two very clean, white
sheets of blotting paper making sure that the side carrying the image is protected
by a sheet of tissue paper. All of these sheets are then put between two pieces of
strong but absorbent pieces of cardboard which are, in turn, weighed down.
It may, however, be better to use boards made of wood shavings which stay perfectly
flat and are particularly absorbent. The drying done with such boards is very rapid
and it will not be necessary to use blotting paper. All that is necessary is to cover
the image with a sheet of tissue paper making sure that the "felt" side of the board,
which is softer, lies against the paper. In fact, such boards will be found to have a
"felt" and a "cloth" side. The boards should be chosen for their perfectly level
surfaces. When drying paper one can pile up many such boards and impressions and
thus it will not be necessary to weigh them down
[* dampening ,
paper].